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Syntheses of cucurbit[6]uril-based metal-organic rotaxane networks by the anion regulation strategy and their proton conduction properties.

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Two new cucurbit[6]uril (CB[6])-based metal-organic rotaxane networks (MORNs) were successfully obtained by tuning the coordination sphere of metal copper clusters. Compounds 1 and 2 exhibited relatively high proton conductivity at… Click to show full abstract

Two new cucurbit[6]uril (CB[6])-based metal-organic rotaxane networks (MORNs) were successfully obtained by tuning the coordination sphere of metal copper clusters. Compounds 1 and 2 exhibited relatively high proton conductivity at 85 °C and 97% relative humidity (RH), providing great promise for fuel cell electrolyte materials.

Keywords: uril based; cucurbit uril; metal organic; based metal; organic rotaxane; rotaxane networks

Journal Title: Dalton transactions
Year Published: 2020

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