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The synthesis and characterization of a series of N-heterocyclic carbene (NHC) complexes of Au(iii), (NHC)AuCl3, is described. High yields are obtained when the corresponding Au(i) species (NHC)AuCl are oxidized with… Click to show full abstract
The synthesis and characterization of a series of N-heterocyclic carbene (NHC) complexes of Au(iii), (NHC)AuCl3, is described. High yields are obtained when the corresponding Au(i) species (NHC)AuCl are oxidized with inexpensive aqua regia. The oxidation is in some cases accompanied by substitution and/or anti addition of Cl2 across the backbone C[double bond, length as m-dash]C bond of unsaturated NHC ligands.
Keywords:
nhc aucl;
aqua regia;
chemistry;
organometallic chemistry
Journal Title: Dalton transactions
Year Published: 2020
Link to full text (if available)
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Journal Title: Dalton transactions
Year Published: 2020
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!