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The N-alkylation of sulfonamides with alcohols in water catalyzed by a water-soluble metal–ligand bifunctional iridium complex [Cp*Ir(biimH2)(H2O)][OTf]2

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A water-soluble dinuclear Cp*Ir complex bearing 4,4′,6,6′-tetrahydroxy-2,2′-bipyrimidine as a bridging ligand was found to be a highly effective catalyst for the N-alkylation of ketones with alcohols in water. Click to show full abstract

A water-soluble dinuclear Cp*Ir complex bearing 4,4′,6,6′-tetrahydroxy-2,2′-bipyrimidine as a bridging ligand was found to be a highly effective catalyst for the N-alkylation of ketones with alcohols in water.

Keywords: alcohols water; alkylation sulfonamides; sulfonamides alcohols; water; water soluble

Journal Title: New Journal of Chemistry
Year Published: 2019

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