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Sulphur–sulphur, sulphur–selenium, selenium–selenium and selenium–carbon bond activation using Fe3(CO)12: an unexpected formation of an Fe2(CO)6 complex containing a μ2,κ3-C,O,Se-ligand

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Four diiron hexacarbonyl-complexes containing dithiolato (5), diselenolato (6), selenolato-thiolato (7) and μ2,κ3-C,O,Se-ligands (8), respectively have been prepared as [FeFe]-hydrogenase mimics. Click to show full abstract

Four diiron hexacarbonyl-complexes containing dithiolato (5), diselenolato (6), selenolato-thiolato (7) and μ2,κ3-C,O,Se-ligands (8), respectively have been prepared as [FeFe]-hydrogenase mimics.

Keywords: sulphur selenium; selenium selenium; selenium carbon; selenium; sulphur sulphur

Journal Title: New Journal of Chemistry
Year Published: 2019

Link to full text (if available)


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