The two diastereoisomers of 4,4′-azobis(4-cyanopentanoic acid) decompose at different rates in aqueous media. The major products (>50%) are amides produced by trapping the ketenimines formed by C–N coupling. Click to show full abstract
The two diastereoisomers of 4,4′-azobis(4-cyanopentanoic acid) decompose at different rates in aqueous media. The major products (>50%) are amides produced by trapping the ketenimines formed by C–N coupling.
               
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