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A novel low-bandgap pyridazine thiadiazole-based conjugated polymer with deep molecular orbital levels

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A pyridazine thiadiazole acceptor (PzT) has been utilised in the synthesis of a novel low band-gap D–A copolymer PTTPz. It is a much stronger acceptor in comparison to BT and… Click to show full abstract

A pyridazine thiadiazole acceptor (PzT) has been utilised in the synthesis of a novel low band-gap D–A copolymer PTTPz. It is a much stronger acceptor in comparison to BT and PyT moieties widely incorporated in the literature. Experimental results reveal that per electronegative N atom that is substituted into the acceptor, an effective HOMO and LUMO stabilization energy of ∼0.2–0.1 eV can be achieved.

Keywords: novel low; thiadiazole based; low bandgap; pyridazine thiadiazole; bandgap pyridazine

Journal Title: Polymer Chemistry
Year Published: 2020

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