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Significant improvement of photocatalytic hydrogen evolution of diketopyrrolopyrrole-based donor–acceptor conjugated polymers through side-chain engineering

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The hydrogen evolution rate of PDPP3B-O4 with butoxy chain was 5.53 mmol h−1 g−1 with 1% Pt loading (λ > 400 nm), increased 110 times than PDPP3B-C8 with octyl chain… Click to show full abstract

The hydrogen evolution rate of PDPP3B-O4 with butoxy chain was 5.53 mmol h−1 g−1 with 1% Pt loading (λ > 400 nm), increased 110 times than PDPP3B-C8 with octyl chain due to wider absorption spectrum and better wettability via side chain engineering.

Keywords: chain engineering; chain; side chain; hydrogen evolution

Journal Title: Polymer Chemistry
Year Published: 2019

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