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Novel nickel–cobalt phosphite with face-sharing octahedra derived electrocatalyst for efficient water splitting

Nickel–cobalt phosphite (CoNiPO) including local structural motifs with face-sharing octahedra shows excellent OER activity. The derivatized electrocatalyst (NiP2@CoNiPO) exhibits high HER activity. DFT calculations indicated the super-exchange effect in CoNiPO… Click to show full abstract

Nickel–cobalt phosphite (CoNiPO) including local structural motifs with face-sharing octahedra shows excellent OER activity. The derivatized electrocatalyst (NiP2@CoNiPO) exhibits high HER activity. DFT calculations indicated the super-exchange effect in CoNiPO can adjust local electronic structure and improve their catalytic activity.

Keywords: nickel cobalt; cobalt phosphite; face sharing; novel nickel; sharing octahedra

Journal Title: Inorganic Chemistry Frontiers
Year Published: 2019

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