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Enynone-enabled migratory insertion and Schmittel cyclization cascade for the synthesis of furan-fused fluorenes

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A new method for the synthesis of furan-/benzo-fused fluorenes through copper(i)-catalyzed coupling of conjugated enynones or α-diazocarbonyl compounds with dialkynylbenzenes has been developed. Click to show full abstract

A new method for the synthesis of furan-/benzo-fused fluorenes through copper(i)-catalyzed coupling of conjugated enynones or α-diazocarbonyl compounds with dialkynylbenzenes has been developed.

Keywords: synthesis furan; enabled migratory; migratory insertion; enynone enabled; fused fluorenes

Journal Title: Organic Chemistry Frontiers
Year Published: 2019

Link to full text (if available)


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