A Rh(i) catalyzed [2 + 2 + 1] cycloaddition of intramolecular diynes and a diazo moiety has been reported, in which the dediazoniation does not occur and the terminal nitrogen… Click to show full abstract
A Rh(i) catalyzed [2 + 2 + 1] cycloaddition of intramolecular diynes and a diazo moiety has been reported, in which the dediazoniation does not occur and the terminal nitrogen of the diazo moiety serves as the N1 unit.
               
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