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Rh(i)-Catalyzed intramolecular [2 + 2 + 1] cycloaddition of diynes with the N-terminal of the diazo group

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A Rh(i) catalyzed [2 + 2 + 1] cycloaddition of intramolecular diynes and a diazo moiety has been reported, in which the dediazoniation does not occur and the terminal nitrogen… Click to show full abstract

A Rh(i) catalyzed [2 + 2 + 1] cycloaddition of intramolecular diynes and a diazo moiety has been reported, in which the dediazoniation does not occur and the terminal nitrogen of the diazo moiety serves as the N1 unit.

Keywords: diynes terminal; diazo; cycloaddition; catalyzed intramolecular; cycloaddition diynes; intramolecular cycloaddition

Journal Title: Organic Chemistry Frontiers
Year Published: 2019

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