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Phosphine-catalyzed fixation of CO2 with γ-hydroxyl alkynone under ambient temperature and pressure: kinetic resolution and further conversion

Phosphine-catalyzed fixation of CO2 with γ-hydroxyl alkynone under ambient temperature and pressure was achieved and the first example of chiral phosphine catalyzed kinetic resolution of propargyl alcohols via carbon dioxide… Click to show full abstract

Phosphine-catalyzed fixation of CO2 with γ-hydroxyl alkynone under ambient temperature and pressure was achieved and the first example of chiral phosphine catalyzed kinetic resolution of propargyl alcohols via carbon dioxide fixation was demonstrated.

Keywords: fixation; phosphine catalyzed; hydroxyl alkynone; catalyzed fixation; co2 hydroxyl; fixation co2

Journal Title: Organic Chemistry Frontiers
Year Published: 2019

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