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Novel asymmetric photodimerization reaction of coumarin derivatives bearing a chiral 2-oxazolidinone auxiliary

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Photodimerization of chiral coumarin-3-carboxamide affords the syn-HT dimer with moderate diastereoselectivity and we propose a mechanism on the basis of DFT calculations. Click to show full abstract

Photodimerization of chiral coumarin-3-carboxamide affords the syn-HT dimer with moderate diastereoselectivity and we propose a mechanism on the basis of DFT calculations.

Keywords: photodimerization; coumarin; novel asymmetric; asymmetric photodimerization; photodimerization reaction; reaction coumarin

Journal Title: RSC Advances
Year Published: 2019

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