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Asymmetric retro-[1,4]-Brook rearrangement of 3-silyl allyloxysilanes via chirality transfer from silicon to carbon

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Asymmetric retro-[1,4]-Brook rearrangement of 3-silyl allyloxysilanes has been developed involving Si-to-C chirality transfer, which is diastereoselective without loss of enantiomeric excess. Click to show full abstract

Asymmetric retro-[1,4]-Brook rearrangement of 3-silyl allyloxysilanes has been developed involving Si-to-C chirality transfer, which is diastereoselective without loss of enantiomeric excess.

Keywords: chirality transfer; rearrangement silyl; asymmetric retro; brook rearrangement; silyl allyloxysilanes; retro brook

Journal Title: RSC Advances
Year Published: 2019

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