"Vinylphosphonites for Staudinger-induced chemoselective peptide cyclization and functionalization† †This work is dedicated to Prof. Ron Raines on the occasion of his 60th birthday. ‡ ‡Electronic supplementary information (ESI) available. See DOI: 10.1039/c9sc01345h"

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Vinylphosphonites for Staudinger-induced chemoselective peptide cyclization and functionalization† †This work is dedicated to Prof. Ron Raines on the occasion of his 60th birthday. ‡ ‡Electronic supplementary information (ESI) available. See DOI: 10.1039/c9sc01345h

Vinylphosphonites react in chemoselective Staudinger-phosphonite reactions (SPhR) with azides to form vinylphosphonamidates for the subsequent modification of cysteine residues in peptides and proteins. Click to show full abstract

Keywords: staudinger induced; vinylphosphonites staudinger; induced chemoselective; peptide cyclization; cyclization functionalization; chemoselective peptide

Journal Title: Chemical Science
Year Published: 2019

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