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A rhodium-catalyzed highly regio- and enantioselective hydroalkynylation generating cis-hydrobenzofuranone-tethered enynes has been developed. The reaction proceeds with a dynamic kinetic head-to-head insertion and symmetry breaking Michael addition cascade. Click to show full abstract
A rhodium-catalyzed highly regio- and enantioselective hydroalkynylation generating cis-hydrobenzofuranone-tethered enynes has been developed. The reaction proceeds with a dynamic kinetic head-to-head insertion and symmetry breaking Michael addition cascade.
Keywords:
alkynes electronic;
enynes terminal;
terminal alkynes;
cyclization enynes;
electronic supplementary;
hydroalkynylative cyclization
Journal Title: Chemical Science
Year Published: 2019
Link to full text (if available)
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Journal Title: Chemical Science
Year Published: 2019
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!