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Controlled scrambling reactions to polyphosphanes via bond metathesis reactions† †Electronic supplementary information (ESI) available. CCDC 1950469–1950486. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c9sc04501e

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Dipyrazolylphosphanes RPpyr2 (5: R = Py; 6: R = BTz; pyr = 1,3-dimethylpyrazolyl) are established as powerful P1-building blocks in P–P bond forming reactions via condensation or P–N/P–P bond metathesis… Click to show full abstract

Dipyrazolylphosphanes RPpyr2 (5: R = Py; 6: R = BTz; pyr = 1,3-dimethylpyrazolyl) are established as powerful P1-building blocks in P–P bond forming reactions via condensation or P–N/P–P bond metathesis reactions with secondary phosphanes.

Keywords: scrambling reactions; bond; metathesis reactions; bond metathesis; controlled scrambling

Journal Title: Chemical Science
Year Published: 2019

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