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Improving LMOF luminescence quantum yield through guest-mediated rigidification

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Rotation of a specific pyridyl ring in LMOF-236 is locked by loading guest molecules into the MOF's pore, improving quantum yield by nearly 400%–an example of a generalizable strategy for… Click to show full abstract

Rotation of a specific pyridyl ring in LMOF-236 is locked by loading guest molecules into the MOF's pore, improving quantum yield by nearly 400%–an example of a generalizable strategy for maximizing quantum yield via guest-packing rigidification.

Keywords: lmof luminescence; rigidification; improving lmof; yield; quantum yield; guest

Journal Title: Journal of Materials Chemistry C
Year Published: 2019

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