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VOPO4·2H2O as a new cathode material for rechargeable Ca-ion batteries.

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VOPO4·2H2O, as a new cathode material for Ca-ion batteries, exhibits a discharge capacity of 100.6 mA h g-1, excellent cycling stability (200 cycles) and good rate performance (42.7 mA h… Click to show full abstract

VOPO4·2H2O, as a new cathode material for Ca-ion batteries, exhibits a discharge capacity of 100.6 mA h g-1, excellent cycling stability (200 cycles) and good rate performance (42.7 mA h g-1 at 200 mA g-1). In situ X-ray diffraction and in situ Raman results demonstrate the calcium-ion-storage mechanism of VOPO4·2H2O is a single-phase reaction based on asymmetric Ca2+ insertion and deinsertion.

Keywords: vopo4 2h2o; new cathode; cathode material; 2h2o new; ion; ion batteries

Journal Title: Chemical communications
Year Published: 2020

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