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Rational regulation of transition metals in polyoxometalate hybrids without noble metal assistance for efficient light-driven H2 production.

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Four new rationally designed polyoxometalate (POM)-based hybrids are reported with a maximum photocatalytic hydrogen evolution rate of 12245.59 μmol g-1 h-1, which outperform all known POM-based metal-organic photocatalysts. Click to show full abstract

Four new rationally designed polyoxometalate (POM)-based hybrids are reported with a maximum photocatalytic hydrogen evolution rate of 12245.59 μmol g-1 h-1, which outperform all known POM-based metal-organic photocatalysts.

Keywords: transition metals; metal; metals polyoxometalate; rational regulation; regulation transition; polyoxometalate hybrids

Journal Title: Chemical communications
Year Published: 2020

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