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The stable cycling of a high-capacity Bi anode enabled by an in situ-generated Li3PO4 transition layer in a sulfide-based all-solid-state battery.

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The most processable solid electrolyte, Li2S-P2S5 (LPS), exhibits the drawback of a limited potential window, which leads to the deterioration of the interface stability and limits the application of high-capacity… Click to show full abstract

The most processable solid electrolyte, Li2S-P2S5 (LPS), exhibits the drawback of a limited potential window, which leads to the deterioration of the interface stability and limits the application of high-capacity anodes, such as those based on Li, Si, and Bi. Here, the in situ formation of a designed artificial solid electrolyte interface provides an effective way to apply low-voltage anodes in solid-state batteries.

Keywords: solid state; stable cycling; cycling high; high capacity

Journal Title: Chemical communications
Year Published: 2020

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