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The Zn(ii) MOF with a tripyridinium-based hexacarboxylate shows direct color change on exposure to small primary amines and UV-assisted color response on exposure to small alcohols. The reversible, group-specific and… Click to show full abstract
The Zn(ii) MOF with a tripyridinium-based hexacarboxylate shows direct color change on exposure to small primary amines and UV-assisted color response on exposure to small alcohols. The reversible, group-specific and size-selective chemochromic/chemophotochromic behaviours are ascribed to spontaneous/photoinduced guest-to-host electron transfer within the unique confined space furnished with electron-deficient sites.
Keywords:
response;
induced photochromic;
chemochromic chemically;
chemically induced;
selective chemochromic;
photochromic response
Journal Title: Chemical communications
Year Published: 2020
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Journal Title: Chemical communications
Year Published: 2020
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!