Longitudinal shape evolution of Ag2S nanoparticles is reported. Initially 9 nm nanospheres turn into faceted rhombic dodecahedrons and elongate to minimize surface energy. The elongated rhombic dodecahedrons show oriented attachments… Click to show full abstract
Longitudinal shape evolution of Ag2S nanoparticles is reported. Initially 9 nm nanospheres turn into faceted rhombic dodecahedrons and elongate to minimize surface energy. The elongated rhombic dodecahedrons show oriented attachments to -104 directions sequentially yielding dimers, linear oligomers, and nanorods. Lateral sides of nanorods fuse to thermodynamically stable nanocubes upon ripening.
               
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