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Multi-charged macrocycles as a platform for rapid and broad spectral photodecomposition of aromatic dyes.

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Four water-soluble macrocycles were chosen to explore the photodecomposition behaviours of quaternized 9-alkoxy-substituted anthracene (AnQA). Significantly, a highly charged macrocyclic skeleton leads to extremely close packing among the anthryl rings,… Click to show full abstract

Four water-soluble macrocycles were chosen to explore the photodecomposition behaviours of quaternized 9-alkoxy-substituted anthracene (AnQA). Significantly, a highly charged macrocyclic skeleton leads to extremely close packing among the anthryl rings, providing a favourable hydrophobic environment for singlet oxygen, leading to rapid oxidation to produce the photoproducts under sunlight irradiation.

Keywords: rapid broad; multi charged; platform rapid; charged macrocycles; photodecomposition; macrocycles platform

Journal Title: Chemical communications
Year Published: 2020

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