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Direct N-formylation of nitroarenes with CO2.

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Herein we describe a straightforward N-formylation of nitroarenes with CO2 to access N-aryl formamides exclusively in the presence of iron and hydrosilane as additives. This protocol showcases a good tolerance… Click to show full abstract

Herein we describe a straightforward N-formylation of nitroarenes with CO2 to access N-aryl formamides exclusively in the presence of iron and hydrosilane as additives. This protocol showcases a good tolerance of a wide range of nitroarenes and nitroheteroarenes.

Keywords: nitroarenes co2; formylation nitroarenes; direct formylation

Journal Title: Chemical communications
Year Published: 2020

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