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Anion-dependent topochemical conversion of CoAl-LDH microplates to hierarchical superstructures of CoOOH nanoplates with controllable orientation.

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Hierarchical superstructures of laterally or vertically oriented CoOOH nanoplates were prepared by topochemical conversion of CoAl-LDH microplates intercalated with CO32- or SO42- anions, respectively. The superstructure of vertically oriented nanoplates… Click to show full abstract

Hierarchical superstructures of laterally or vertically oriented CoOOH nanoplates were prepared by topochemical conversion of CoAl-LDH microplates intercalated with CO32- or SO42- anions, respectively. The superstructure of vertically oriented nanoplates exhibited better electrocatalytic performance as compared to the lateral counterpart, attributable to the enlarged accessible surface area and promoted reaction kinetics.

Keywords: topochemical conversion; coooh nanoplates; conversion coal; coal ldh; hierarchical superstructures; ldh microplates

Journal Title: Chemical communications
Year Published: 2020

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