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An ester electrolyte for lithium-sulfur batteries capable of ultra-low temperature cycling.

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A novel lithium bis(fluorosulfonyl)imide in a methyl propionate/fluoroethylene carbonate (LiFSI MP/FEC) electrolyte was designed for high compatibility with the Li metal and sulfurized polyacrylonitrile (SPAN). The resulting Li||SPAN cells can… Click to show full abstract

A novel lithium bis(fluorosulfonyl)imide in a methyl propionate/fluoroethylene carbonate (LiFSI MP/FEC) electrolyte was designed for high compatibility with the Li metal and sulfurized polyacrylonitrile (SPAN). The resulting Li||SPAN cells can charge and discharge at -20 °C and -40 °C with over 91% and 78% room temperature capacity retention.

Keywords: electrolyte lithium; temperature; ester electrolyte; sulfur batteries; lithium sulfur; lithium

Journal Title: Chemical communications
Year Published: 2020

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