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Reaction of a silylene-functionalized Si6 siliconoid with CO in the presence of catalytic quantities of a nickel(0) complex results in the complete cleavage of the CO triple bond, but preserves… Click to show full abstract
Reaction of a silylene-functionalized Si6 siliconoid with CO in the presence of catalytic quantities of a nickel(0) complex results in the complete cleavage of the CO triple bond, but preserves the Si6 scaffold with an exohedrally incorporated Si[double bond, length as m-dash]C enol ether bridge. The uncompromised cluster core emphasizes the role of the so-called benzpolarene motif as the energetic silicon pendants of benzene in carbon chemistry.
Keywords:
length dash;
dash enol;
bond;
bond length;
complete cleavage;
double bond
Journal Title: Chemical communications
Year Published: 2020
Link to full text (if available)
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Journal Title: Chemical communications
Year Published: 2020
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!