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Monocarboxylate-driven structural growth in Calix[n]arene-polyoxotitanate hybrid systems: utility in hydrogen production from water.

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A carboxylate-driven assembly strategy has been developed for the first time to build calix[n]arene-based polyoxotitanate clusters with tuneable nuclearity and structures. Photocatalytic studies revealed that these clusters exhibit structural-dependent H2… Click to show full abstract

A carboxylate-driven assembly strategy has been developed for the first time to build calix[n]arene-based polyoxotitanate clusters with tuneable nuclearity and structures. Photocatalytic studies revealed that these clusters exhibit structural-dependent H2 evolution ability with a maximum rate up to 415.11 μmol h-1 g-1, which is almost the highest recorded in polyoxotitanate clusters.

Keywords: calix arene; calix; driven structural; structural growth; monocarboxylate driven

Journal Title: Chemical communications
Year Published: 2020

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