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Addition of HOTf to a mixture of CoIII(BDPP)(O2˙) (1, H2BDPP = 2,6-bis((2-(S)-diphenylhydroxylmethyl-1-pyrrolidinyl)methyl)pyridine) and Cp*2Fe produced H2O2 in high yield implying formation of CoIII(BDPP)(OOH) (3), and reaction of Sc(OTf)3 with the… Click to show full abstract
Addition of HOTf to a mixture of CoIII(BDPP)(O2˙) (1, H2BDPP = 2,6-bis((2-(S)-diphenylhydroxylmethyl-1-pyrrolidinyl)methyl)pyridine) and Cp*2Fe produced H2O2 in high yield implying formation of CoIII(BDPP)(OOH) (3), and reaction of Sc(OTf)3 with the same mixture gave a peroxo-bridged CoIII/ScIII 5. These findings demonstrate the ambiphilic property of CoIII-superoxo 1.
Keywords:
iii superoxo;
coiii;
ambiphilicity mononuclear;
superoxo complex;
cobalt iii;
mononuclear cobalt
Journal Title: Chemical communications
Year Published: 2020
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Journal Title: Chemical communications
Year Published: 2020
Link to full text (if available)
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recommendations!