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The structure-defining incorporation of chloride in methyllithium dimers.

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We herein present two polymeric solid state structures of pmdta-stabilized methyllithium with co-existing dimeric and tetrameric units, exhibiting partial incorporation of nearly omnipresent LiCl selectively in the dimeric entities. An… Click to show full abstract

We herein present two polymeric solid state structures of pmdta-stabilized methyllithium with co-existing dimeric and tetrameric units, exhibiting partial incorporation of nearly omnipresent LiCl selectively in the dimeric entities. An unexpected interconnecting contact from these positions to a neighboring tetrameric unit is observed.

Keywords: chloride methyllithium; defining incorporation; incorporation; structure defining; methyllithium; incorporation chloride

Journal Title: Chemical communications
Year Published: 2020

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