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The oxygenation of a benzyl ligand in [PdBnCl(cod)] was dramatically accelerated by using secondary phosphine oxides (SPOs), selectively affording either BnOOH or BnOH, depending on the concentration of O2. The… Click to show full abstract
The oxygenation of a benzyl ligand in [PdBnCl(cod)] was dramatically accelerated by using secondary phosphine oxides (SPOs), selectively affording either BnOOH or BnOH, depending on the concentration of O2. The SPOs coordinate to palladium in the form of phosphinous acids, operating as Brønsted acids to facilitate further reaction with O2.
Keywords:
secondary phosphine;
oxygenation benzyl;
benzyl ligand
Journal Title: Chemical communications
Year Published: 2020
Link to full text (if available)
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Journal Title: Chemical communications
Year Published: 2020
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!