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Generalized reactivity descriptor of defective carbon catalysts for acetylene hydrochlorination: the ratio of sp2 : sp3 hybridization.

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The golden section point in carbon catalysts for acetylene hydrochlorination has been determined. The surface sp2 : sp3 ratio of two types of carbon catalysts, including nanodiamond- and graphite-oriented carbons, both have… Click to show full abstract

The golden section point in carbon catalysts for acetylene hydrochlorination has been determined. The surface sp2 : sp3 ratio of two types of carbon catalysts, including nanodiamond- and graphite-oriented carbons, both have a volcano relationship with the catalytic performance for acetylene hydrochlorination, and the optimized ratios are both around 32-35%.

Keywords: acetylene hydrochlorination; carbon catalysts; sp2 sp3; catalysts acetylene

Journal Title: Chemical communications
Year Published: 2020

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