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Poly(dimethylsiloxane) and oligo(dimethylsiloxane) solvent effects on aromatic donor-acceptor interactions.

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Solvents with a wide range of polarities, including poly(dimethylsiloxane) and oligo(dimethylsiloxane), were used to evaluate aromatic donor-acceptor interactions between pyrene and pyromellitic diimide derivatives. The donor-acceptor interactions were stronger in… Click to show full abstract

Solvents with a wide range of polarities, including poly(dimethylsiloxane) and oligo(dimethylsiloxane), were used to evaluate aromatic donor-acceptor interactions between pyrene and pyromellitic diimide derivatives. The donor-acceptor interactions were stronger in siloxane solvents than in aliphatic solvents, possibly because of the poor solubility of the aromatics in siloxanes.

Keywords: acceptor interactions; donor acceptor; dimethylsiloxane oligo; dimethylsiloxane; poly dimethylsiloxane

Journal Title: Chemical communications
Year Published: 2021

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