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Surface morphology-induced spin-crossover-inactive high-spin state in a coordination framework.

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Here we report a surface morphology-induced spin state control in ultrathin films of a spin-crossover (SCO) material. The surface microstructure of film domains exhibited selectivity, to stabilize the SCO-active high-spin… Click to show full abstract

Here we report a surface morphology-induced spin state control in ultrathin films of a spin-crossover (SCO) material. The surface microstructure of film domains exhibited selectivity, to stabilize the SCO-active high-spin (HS) or SCO-inactive high-spin (HS2) states. To date, the latter has only been confirmed in the bulk counterpart at gigapascal pressure.

Keywords: induced spin; high spin; spin state; spin; morphology induced; surface morphology

Journal Title: Chemical communications
Year Published: 2021

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