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An octahedral polyoxomolybdate-organic molecular cage.

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An unprecedented Mo-organic molecular cage built on interesting {MoVI2O5} secondary building blocks and BTC ligands, which has been successfully synthesized and systematically characterized, presents the first example of an isopolyoxomolybdates(vi)-organic… Click to show full abstract

An unprecedented Mo-organic molecular cage built on interesting {MoVI2O5} secondary building blocks and BTC ligands, which has been successfully synthesized and systematically characterized, presents the first example of an isopolyoxomolybdates(vi)-organic molecular cage. An investigation into the related Cs+-exchange experiment was performed in detail.

Keywords: polyoxomolybdate organic; organic molecular; octahedral polyoxomolybdate; molecular cage

Journal Title: Chemical communications
Year Published: 2021

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