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Quasi-operando quantification of Cu(II) ions in Cu-SSZ-13 catalyst by an NH3 temperature-programmed reduction method.

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A quasi-operando NH3 temperature-programmed reduction method (NH3-TPR), with N2:Cu = 1:1, is developed to quantify total Cu(ii) ions in Cu-SSZ-13 quenched from SCR-relevant reactions, and its accuracy is confirmed by… Click to show full abstract

A quasi-operando NH3 temperature-programmed reduction method (NH3-TPR), with N2:Cu = 1:1, is developed to quantify total Cu(ii) ions in Cu-SSZ-13 quenched from SCR-relevant reactions, and its accuracy is confirmed by in situ EPR. [Cu(OH)]+-Z and Cu2+-2Z can be further distinguished by NH3 reduction temperatures, and their different reducibility in SCR is revealed.

Keywords: reduction; nh3 temperature; temperature programmed; quasi operando; reduction method; programmed reduction

Journal Title: Chemical communications
Year Published: 2021

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