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Highly stable zinc metal anode enabled by oxygen functional groups for advanced Zn-ion supercapacitors.

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Konjac glucomannan (KGM) featuring abundant oxygen functional groups has been elaborately designed to enhance Zn reversibility. Importantly, -OH and C[double bond, length as m-dash]O groups as active sites could redistribute… Click to show full abstract

Konjac glucomannan (KGM) featuring abundant oxygen functional groups has been elaborately designed to enhance Zn reversibility. Importantly, -OH and C[double bond, length as m-dash]O groups as active sites could redistribute the Zn2+ concentration field and modulate the plating/stripping rate, further enabling uniform Zn deposition without dendrite growth. The Zn@KGM anode enables an advanced Zn-ion supercapacitor to deliver an impressive rate performance and cycling stability (up to 5000 cycles accompanied by a coulombic efficiency of 99.8%).

Keywords: oxygen functional; advanced ion; anode; highly stable; functional groups

Journal Title: Chemical communications
Year Published: 2020

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