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Synthesis and crystal packing of perylene-derivatives with extreme sterically demanding pentaphenylbenzene bay-substituents.

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An unprecedented library of single and double bay-substituted perylene-pentaphenylbenzenes (PPBs) is presented. An extreme core-distortion as well as successful elimination of aggregation interactions of perylenes was confirmed by X-ray analysis.… Click to show full abstract

An unprecedented library of single and double bay-substituted perylene-pentaphenylbenzenes (PPBs) is presented. An extreme core-distortion as well as successful elimination of aggregation interactions of perylenes was confirmed by X-ray analysis. The isomerically pure perylene-PPB hybrids show remarkable differences in their photophysical properties with respect to their regiochemistry as well as different peri-functionalization.

Keywords: perylene derivatives; crystal packing; bay; packing perylene; perylene; synthesis crystal

Journal Title: Chemical communications
Year Published: 2021

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