An unprecedented library of single and double bay-substituted perylene-pentaphenylbenzenes (PPBs) is presented. An extreme core-distortion as well as successful elimination of aggregation interactions of perylenes was confirmed by X-ray analysis.… Click to show full abstract
An unprecedented library of single and double bay-substituted perylene-pentaphenylbenzenes (PPBs) is presented. An extreme core-distortion as well as successful elimination of aggregation interactions of perylenes was confirmed by X-ray analysis. The isomerically pure perylene-PPB hybrids show remarkable differences in their photophysical properties with respect to their regiochemistry as well as different peri-functionalization.
               
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