The axial chirality of the non-planar conjugated triene in vitamin D3 was uncovered for the first time. An ECD titration method was used not only for conformational analysis of vitamin… Click to show full abstract
The axial chirality of the non-planar conjugated triene in vitamin D3 was uncovered for the first time. An ECD titration method was used not only for conformational analysis of vitamin D but also for sensitive detection of hydrogen-bonding interaction in solution. It provides a sensitive approach to predict cocrystal formation.
               
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