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A halogen-bonded supramolecular ladder comprised of a novel pyrimidine-based cyclobutane photoproduct synthesized in the organic solid state via a [2 + 2] photoreaction is reported. The photoproduct rctt-tetrakis(5′-pyrimidyl)cyclobutane functions as… Click to show full abstract
A halogen-bonded supramolecular ladder comprised of a novel pyrimidine-based cyclobutane photoproduct synthesized in the organic solid state via a [2 + 2] photoreaction is reported. The photoproduct rctt-tetrakis(5′-pyrimidyl)cyclobutane functions as rungs while the linear divergent halogen-bond donor 1,4-diiodoperchlorobenzene acts as the rails. Our report also confirms the structure and stereochemistry of the tetrapyrimidyl cyclobutane ring system.
Keywords:
halogen bonded;
supramolecular ladder;
synthesized organic;
bonded supramolecular;
halogen;
cyclobutane
Journal Title: CrystEngComm
Year Published: 2020
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Journal Title: CrystEngComm
Year Published: 2020
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!