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Guest-dependent single-crystal-to-single-crystal transformations in porous adamantane-bearing macrocycles

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An adamantane-bearing macrocycle showed permanent intrinsic porosity and adsorption of small organic compounds in a single-crystal-to-single-crystal fashion. Guest uptake by the porous crystals gave rise to the structural transformation of… Click to show full abstract

An adamantane-bearing macrocycle showed permanent intrinsic porosity and adsorption of small organic compounds in a single-crystal-to-single-crystal fashion. Guest uptake by the porous crystals gave rise to the structural transformation of the supramolecular organic framework, resulting in the change of shape and size of one-dimensional pores.

Keywords: single crystal; guest dependent; crystal single; adamantane bearing

Journal Title: CrystEngComm
Year Published: 2021

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