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[Bmmim]6[In10Se16Cl4]·(MIm)2: an organic-ligand free discrete T3 cluster for efficient hydrogen evolution under visible light irradiation.

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An indium selenide [Bmmim]6[In10Se16Cl4]·(MIm)2 (Bmmim = 1-butyl-2,3-dimethylimidazolium, MIm = 1-methylimidazole) cluster has been synthesized and characterized. The discrete T3 cluster could be stably dispersed in dimethyl sulfoxide, exhibiting photocatalytic hydrogen… Click to show full abstract

An indium selenide [Bmmim]6[In10Se16Cl4]·(MIm)2 (Bmmim = 1-butyl-2,3-dimethylimidazolium, MIm = 1-methylimidazole) cluster has been synthesized and characterized. The discrete T3 cluster could be stably dispersed in dimethyl sulfoxide, exhibiting photocatalytic hydrogen evolution activity at least six times that of the pristine in the solid state due to the exposure of more active sites.

Keywords: bmmim in10se16cl4; in10se16cl4 mim; mim; hydrogen evolution; discrete cluster; cluster

Journal Title: Dalton transactions
Year Published: 2020

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