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Two FeII8L12 cubic metal-organic cages were constructed with semi-rigid ligands and they further self-assembled into supramolecular assemblies with three different porous cavities. The supramolecular assemblies showed synergistic adsorption of I2… Click to show full abstract
Two FeII8L12 cubic metal-organic cages were constructed with semi-rigid ligands and they further self-assembled into supramolecular assemblies with three different porous cavities. The supramolecular assemblies showed synergistic adsorption of I2 and TTF, and their solid state spin-crossover behaviors were influenced by the adsorbed guest molecules.
Keywords:
supramolecular assemblies;
spin crossover;
metal organic;
organic cages;
synergistic adsorption;
cubic metal
Journal Title: Dalton transactions
Year Published: 2020
Link to full text (if available)
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Journal Title: Dalton transactions
Year Published: 2020
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!