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Isostructural mesoporous ionic crystals as a tunable platform for acid catalysis.

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Eleven isostructural mesoporous ionic crystals (meso-PICs) are synthesized. The initial activities of the Barbier-Grignard reaction, which is a typical C-C bond formation reaction, catalyzed by the meso-PICs are dependent on… Click to show full abstract

Eleven isostructural mesoporous ionic crystals (meso-PICs) are synthesized. The initial activities of the Barbier-Grignard reaction, which is a typical C-C bond formation reaction, catalyzed by the meso-PICs are dependent on the acid dissociation constant of the aqua ions of Mn+ and the types of polyoxometalates, which construct the meso-PICs.

Keywords: isostructural mesoporous; ionic crystals; meso pics; mesoporous ionic; crystals tunable; tunable platform

Journal Title: Dalton transactions
Year Published: 2020

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