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Dense π-stacking of flexible ligands fixed in interpenetrating Zn(ii) MOF exhibiting long-lasting phosphorescence and efficient carrier transport.

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Three-fold interpenetrating Zn(ii) MOF with the dense π-stacking of flexible ligands exhibit long-lived phosphorescence emission up to 91 ms at room temperature. Photoelectric measurements show efficient electro-hole separation based on… Click to show full abstract

Three-fold interpenetrating Zn(ii) MOF with the dense π-stacking of flexible ligands exhibit long-lived phosphorescence emission up to 91 ms at room temperature. Photoelectric measurements show efficient electro-hole separation based on the long lifetime of triplet state exciton.

Keywords: stacking flexible; flexible ligands; phosphorescence; dense stacking; interpenetrating mof

Journal Title: Dalton transactions
Year Published: 2020

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