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A catalytic study of water dispersed gold nanoparticles for the hydrolytic oxidation of diorganosilanes - en route formation of a Pickering catalyst and synthesis of tetraorganodisiloxane-1,3-diols.

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Water-dispersed gold nanoparticles decorated with an amphiphilic cyclotetrasiloxane scaffold hold promise for the catalytic transformation of diorganosilanes to tetraorganodisiloxane-1,3-diols, (RR1SiOH)2O [R = Me or Ph R1 = Ph, cyclo-Hex] via… Click to show full abstract

Water-dispersed gold nanoparticles decorated with an amphiphilic cyclotetrasiloxane scaffold hold promise for the catalytic transformation of diorganosilanes to tetraorganodisiloxane-1,3-diols, (RR1SiOH)2O [R = Me or Ph R1 = Ph, cyclo-Hex] via en route formation of a Pickering emulsion. The recognition ability of these compounds toward Cl- ions reveals 2 : 1 receptor-anion complexation.

Keywords: route formation; water dispersed; gold nanoparticles; formation pickering; dispersed gold; tetraorganodisiloxane diols

Journal Title: Dalton transactions
Year Published: 2020

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