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Recognition, mechanistic investigation and applications for the detection of biorelevant Cu2+/Fe2+/Fe3+ ions by ruthenium(II)-polypyridyl based fluorescent sensors.

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The present article focuses on fluorescent probes based on Ru(ii)-polypyridyl fragments connected to different chelates, their significant roles in coordination chemistry and their applications in the selective recognition of biorelevant… Click to show full abstract

The present article focuses on fluorescent probes based on Ru(ii)-polypyridyl fragments connected to different chelates, their significant roles in coordination chemistry and their applications in the selective recognition of biorelevant Cu2+ and Fe2+/Fe3+ ions. A critical analysis of the detection of metal ions by both "turn-on" and "turn-off" emission, properties, mechanism and applications of these sensors is presented. Emphasis has also been laid on the efficiency, selectivity and specificity of these sensors towards biologically important Cu2+ and Fe2+/Fe3+ ions.

Keywords: fe2 fe3; fe3 ions; cu2 fe2; biorelevant cu2

Journal Title: Dalton transactions
Year Published: 2021

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