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A pentadentate Schiff-base ligand 3,5Cl-L2- and NCSe- form an iron(iii) mononuclear complex, namely [Fe(3,5Cl-L)(NCSe)], which shows a thermally induced spin crossover with a broad hysteresis width of 24 K between… Click to show full abstract
A pentadentate Schiff-base ligand 3,5Cl-L2- and NCSe- form an iron(iii) mononuclear complex, namely [Fe(3,5Cl-L)(NCSe)], which shows a thermally induced spin crossover with a broad hysteresis width of 24 K between 123 K (warming) and 99 K (cooling). Analogous complexes of the [Fe(3,5X-L)(Y)] type, where X = Cl or Br and Y = Cl-, N3-, NCS-, and NCSe-, are high-spin over the whole temperature interval.
Keywords:
complex showing;
spin crossover;
hysteresis;
crossover iron;
iii complex;
iron iii
Journal Title: Dalton transactions
Year Published: 2020
Link to full text (if available)
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Journal Title: Dalton transactions
Year Published: 2020
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!