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Mechanochemical synthesis of Cu(i)-N-heterocyclic carbene complexes

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We report a general, operationally simple and scalable mechanochemical method for the synthesis of [Cu(Cl)(NHC)] complexes. This solid-state and solvent-less methodology was shown to be applicable to a wide range… Click to show full abstract

We report a general, operationally simple and scalable mechanochemical method for the synthesis of [Cu(Cl)(NHC)] complexes. This solid-state and solvent-less methodology was shown to be applicable to a wide range of NHC ligand precursors, allowing access to complexes of the type [Cu(Cl)(NHC)] under aerobic conditions and with minimised environmental impact.

Keywords: carbene complexes; chemistry; mechanochemical synthesis; synthesis heterocyclic; synthesis; heterocyclic carbene

Journal Title: Green Chemistry
Year Published: 2020

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