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Biorenewable dihydrolevoglucosenone (Cyrene™) is used as an effective dipolar aprotic solvent for Cu(0) wire-mediated RDRP of various monomers without external deoxygenation being applied. The solvent is used to give products… Click to show full abstract
Biorenewable dihydrolevoglucosenone (Cyrene™) is used as an effective dipolar aprotic solvent for Cu(0) wire-mediated RDRP of various monomers without external deoxygenation being applied. The solvent is used to give products with a broad range of molar masses (Mn ∼ 700–28 000), in situ chain extension and as low as 7.8 × 10−4 eq. of [Cu(II)Br2] relative to initiator.
Keywords:
without external;
dihydrolevoglucosenone cyrene;
wire mediated;
external deoxygenation;
solvent wire;
solvent
Journal Title: Green Chemistry
Year Published: 2020
Link to full text (if available)
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Journal Title: Green Chemistry
Year Published: 2020
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!